Baker et al (1993) (p236) "Species such as Mn, Fe, Cu, Zn, and many others, may exhibit depressed element/heat ratios in diffusely venting fluids as a consequence of the precipitation of sulfide minerals due to cooling, and increased pH, oxygen concentration, and residence time that occurs when souce fluids are diluted with seawater within the interstices of the basalt seafloor." Good intro prose in Butterfield et al (1990) p.1 -- p.12,898b -- Assumption of zero magnesium based on experimental water-rock results